• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    This invention relates to analytical chemistry and can be used in potentiometric analysis. The aim of the invention is to accelerate the process of determining the concentration of ions in solutions. The integral sensitive element 1, consisting of sensitive parts of ion-selective electrodes 2-4, made in the form of capillaries made of sensitive glass, contacts the analyzed solution 5 through the sensitive part 3. To calibrate the integral sensitive element, a potential difference is measured between reference electrodes 7 and 8 and the value of this potential is used to calculate the slope of the electrode characteristic of sensitive elements without introducing a reference solution into the sensitive part, which taktirunmtsuyu with the test solution. 1 il. CO i: O4
    公开号:SU1333244A3
    申请号:SU823409905
    申请日:1982-03-12
    公开日:1987-08-23
    发明作者:Дароци Янош；Эрдельи Янош；Хаваш Ене；Кечкеш Лайош；Мюллер Хенрик；Ньиро Каталин；Такач Ферену
    申请人:Раделкиш Электрокемиаи Мюсердьярто Севеткезет (Инопредприятие)；
    IPC主号:
    专利说明:

    The invention relates to the field of analytical chemistry and can be used in potentiometric methods for the analysis of aqueous solutions.
    The aim of the invention is to accelerate the determination of the concentration of ions in solutions.
    The drawing shows a diagram of the device.
    The integral sensor element 1 is composed of sensitive parts of ion-selective electrodes 2-4, made in the form of capillaries made of ion-sensitive glass. The sensing part 3 is connected by means of the analyzed sample 5 with the internal electrolyte of the reference Electrode 6.
    The sensitive part 2 is connected by means of a reference solution containing a certain known amount of detectable ions, for example, a buffer in the case of a pH-sensitive sensor, with a reference electrode 7. Similarly, the sensitive part 4 is connected with another reference solution to the reference electrode 8. Sensitive parts 2-4 are placed in electrolyte 9, which provides galvanic communication between these parts.
    The device works as follows.
    The analyzed solution 5 enters the sensitive part of the integral .1 sensitive element 1, and the potential difference between
    Or N. Egorova 3852/58
    Compiled by A. Fedoseev Tehred L. Serdyukova
    Corr Podpi
    . Circulation 776 VNIIPI USSR State Committee
    for inventions and discoveries 113035, Moscow, Zh-35, Raushsk nab., 4/5
    Production and printing company, Uzhgorod, Projecto st., 4
    comparison electrodes 6 and 7 and 6 and 8. To calibrate the integral sensitive element, it is necessary to measure the potential difference between the electrodes 7 and 8 comparison and calculate the slope of the electrode characteristics of the sensitive elements by contacting the analyzed solution .
    权利要求:
    Claims (1)
    [1]
    Invention Formula
    A device for potentiometric determination of the concentration of ions in solutions, containing an electrochemical cell and an electronic signal processing unit, characterized in that, in order to speed up the determination process, two sensitive parts of the ion-selective electrode are located in the electrochemical cell, one of which is connected by means of an analyzed sample with a reference electrode through its electrolyte, and another through a reference solution is connected to another comparison electrode through its electrolyte, part of the ion electrons are electrically connected by an internal electrolyte between themselves and form an integral sensitive
    made identical from a single material sample.
    Proofreader N. Korol Subscription
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    同族专利:
    公开号 | 公开日
    US4440619A|1984-04-03|
    EP0060533B1|1988-11-30|
    BR8201284A|1983-01-18|
    AT39026T|1988-12-15|
    JPS57161546A|1982-10-05|
    DD202213A5|1983-08-31|
    EP0060533A3|1985-01-09|
    DE3279252D1|1989-01-05|
    DK95682A|1982-09-14|
    PL136836B1|1986-03-31|
    PL235401A1|1982-10-25|
    EP0060533A2|1982-09-22|
    HU181287B|1983-06-28|
    YU53282A|1984-12-31|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US3539455A|1965-10-08|1970-11-10|Leland C Clark Jr|Membrane polarographic electrode system and method with electrochemical compensation|
    US3838034A|1968-04-22|1974-09-24|Gen Electric|Apparatus for detection of catalase-containing bacteria|
    JPS616938B2|1978-03-10|1986-03-03|Olympus Optical Co|
    US4318885A|1979-09-10|1982-03-09|Olympus Optical Co., Ltd.|Liquid treating device for chemical analysis apparatus|HU180405B|1981-03-26|1983-03-28|Nii Ex I Avtomobil Elektroobor|Device for individual feeding winding units to winding machines|
    JPH0736274Y2|1987-05-15|1995-08-16|ベックマンインスツルメンツインコーポレーテッド|Improved flow cell|
    US5502388A|1993-02-04|1996-03-26|Hoechst Aktiengesellschaft|Method of measuring the pH value of a test solution with glass-electrode measuring cells and of simultaneously calibrating the measuring cells|
    DE102004015084A1|2004-01-21|2005-08-18|Winfried Schellbach|pH measurement method for use with a reference diaphragm measurement system in which voltages between rigid leads connected to measurement electrodes and a reference diaphragm are measured to determine an unknown solution pH|
    US8551311B2|2006-09-06|2013-10-08|Hach Company|Ionic probe|
    US8398835B2|2006-03-23|2013-03-19|Hach Company|Unitary ionic probe|
    BRPI0818555A2|2007-10-19|2015-04-22|Hach Co|Multi-electrode ion meter, and Multi-electrode ion probe|
    KR100974564B1|2008-05-22|2010-08-06|한국원자력연구원|Reference Electrode With Self-Calibrated Function And Automatic Electrochemical Potential Correction Apparatus Using The Same|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    HU8181639A|HU181287B|1981-03-13|1981-03-13|Electroanalytic measuring arrangement|
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